Concentrated Platinum‐Gallium Nanoalloy for Hydrogen Production from the Catalytic Steam Reforming of Ethanol

نویسندگان

چکیده

The steam reforming of ethanol (SRE) is a key process for the production H2 and other vital hydrocarbons. present work describes synthesis Platinum-Gallium (Pt−Ga) nanoalloys supported on mesostructured cellular foam (MCF-17) via ultrasound-assisted impregnation method. Ga was substituted with Pt in different wt.% i. e. Pt/MCF-17, Pt99.9Ga0.1/MCF-17, Pt99Ga1/MCF-17, Pt90Ga10/MCF-17 evaluated towards SRE at temperature range 473K-773 K hydrogen (H2), acetaldehyde (CH3CHO), diethylether (DEE), ethylene (C2H4), carbon monoxide (CO), dioxide (CO2), methane (CH4), ethane (C2H6). activity formation rate catalyst were observed to be 68.1 % 3047.2 nmole g−1 sec−1, which 9.8 4.5 times more than Pt/MCF-17 counterparts. Moreover, as from DRIFTS, NH3-TPD XPS studies showed high interaction electron deficit state resulted increased dehydrogenating acidic properties that higher yield H2.

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ژورنال

عنوان ژورنال: Chemcatchem

سال: 2022

ISSN: ['1867-3899', '1867-3880']

DOI: https://doi.org/10.1002/cctc.202200717